Synthesis of Fe-THC MOFs and functionalizing MOFs by MXenes for the selective removal of lead(<scp>ii</scp>) ions from wastewater
Irfan Ijaz, Aysha Bukhari, Ezaz Gilani, Ammara Nazir, Hina Zain
Abstract
at 305 K and pH 4.5. The sorption kinetics obeys the pseudo-second-order kinetic model, and the sorption isotherms fit the Langmuir isotherm model. This finding suggests monolayer sorption on Fe-THC/MXene, and the rate-controlling step is chemisorption. Thermodynamic findings exhibit that sorption was a spontaneous and exothermic process. The sorption process can selectively adsorb Pb ions from aqueous media. After five adsorption-desorption tests, the adsorption efficiency of Fe-THC/MXene was still high. The sorption mechanism of lead on Fe-THC was mainly due to the interaction of lead ions with -F and -O ions and porosity of the Fe-THC/MXene composite. The -O and -F ions were derived from MXene, while the porosity was derived from the MOFs of composites. These findings confirmed that Fe-THC/MXene enables rapid, efficient, and selective elimination of lead from wastewater, which is of practical importance.