Characteristic guaiane sesquiterpenes from <i>Daphne penicillata</i> and ECD/NMR-based assignment of C-1 configuration
Peng Zhao, Ben-Song Xin, Shu-Yan Qin, Zhiyuan Li, Bin Lin, Guo‐Dong Yao, Shao‐Jiang Song, Xiao‐Xiao Huang
Abstract
40 compounds including the first C17 homo-guaiane sesquiterpene (1) were isolated from Daphne penicillata and an efficient method using ECD/NMR strategy to access the C-1 configuration of characteristic guaiane sesquiterpenes has been developed.
Topics & Concepts
SesquiterpeneChemistryStereochemistryTraditional and Medicinal Uses of AnnonaceaePhytochemistry and Biological ActivitiesBioactive Natural Diterpenoids Research