Direct Aerobic Generation of a Ferric Hydroperoxo Intermediate Via a Preorganized Secondary Coordination Sphere
Kate A. Jesse, Sophie W. Anferov, Kelsey A. Collins, Juan A. Valdez-Moreira, Maia E. Czaikowski, Alexander S. Filatov, John S. Anderson
Abstract
ligand radical via ligand-based transfer of an H atom. This system displays oxidative reactivity and ultimately releases hydrogen peroxide, providing insight on how secondary coordination sphere interactions influence the evolution of oxidizing intermediates in Fe-mediated aerobic oxidations.
Topics & Concepts
Coordination sphereChemistryLigand (biochemistry)Coordination complexOxidizing agentReactivity (psychology)PhotochemistryProtonElectron transferMetalCoordination numberOuter sphere electron transferRadicalPrimary (astronomy)Combinatorial chemistryStereochemistryOrganic chemistryIonAstronomyPathologyAlternative medicineQuantum mechanicsBiochemistryMedicineReceptorPhysicsMetal-Catalyzed Oxygenation MechanismsPorphyrin and Phthalocyanine ChemistryMetal complexes synthesis and properties