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Effects of surface acid–base properties of ZrO2 on the direct synthesis of DMC from CO2 and methanol: A combined DFT and experimental study

Xuhui Wang, Jinxian Zhao, Ying Li, Shouying Huang, Jiangwei An, Ruina Shi, Yongli Pei, Zhong Li, Jun Ren

2020Chemical Engineering Science50 citationsDOI

Topics & Concepts

Dimethyl carbonateCatalysisLewis acids and basesMethanolChemistryFourier transform infrared spectroscopyBase (topology)Monoclinic crystal systemAcid strengthDesorptionBrønsted–Lowry acid–base theoryYield (engineering)Tetragonal crystal systemPhysical chemistryInorganic chemistryChemical engineeringOrganic chemistryMaterials scienceAdsorptionMoleculeCrystal structureZeoliteMathematicsMetallurgyEngineeringMathematical analysisCarbon dioxide utilization in catalysisMetal-Organic Frameworks: Synthesis and ApplicationsCatalysts for Methane Reforming
Effects of surface acid–base properties of ZrO2 on the direct synthesis of DMC from CO2 and methanol: A combined DFT and experimental study | Litcius