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Microstructural origin of selective water oxidation to hydrogen peroxide at low overpotentials: a study on Mn-alloyed TiO<sub>2</sub>

Jiahui Li, Devan Solanki, Qianhong Zhu, Xin Shen, Grace Callander, Jae‐Hong Kim, Yaogang Li, Hongzhi Wang, Shu Hu

2021Journal of Materials Chemistry A30 citationsDOI

Abstract

Mn-alloyed TiO 2 coatings prepared by atomic layer deposition (ALD) and annealing acheived stable two-electron selective water oxidation to produce hydrogen peroxide, where the desired products require thermodynamically unfavorable pathways.

Topics & Concepts

Hydrogen peroxideAtomic layer depositionAnnealing (glass)Inorganic chemistryMaterials scienceChemical engineeringHydrogenPeroxideDeposition (geology)ChemistryLayer (electronics)MetallurgyNanotechnologyOrganic chemistryEngineeringPaleontologyBiologySedimentCatalytic Processes in Materials ScienceElectrocatalysts for Energy ConversionElectronic and Structural Properties of Oxides
Microstructural origin of selective water oxidation to hydrogen peroxide at low overpotentials: a study on Mn-alloyed TiO<sub>2</sub> | Litcius