NiFe-PANI composites synthesized by electrodeposition for enhanced photocatalytic degradation of diclofenac sodium from wastewater
Nadjem Lakhdari, Delloula Lakhdari, Mohammed Berkani, Yasser Vasseghian, Fatsah Moulaï, Mohammed M. Rahman, Rabah Boukherroub, Tejraj M. Aminabhavi
Abstract
A simple inexpensive approach was used to synthesize NiFe-PANI nanocomposites and used for photodegradation of diclofenac sodium (DCF) in water sources. Morphological, optical, structural, and catalytic properties of the nanocomposites were investigated using X-ray diffraction (XRD) to confirm the cubic structure of NiFe nanoparticles and Fourier-transform infrared spectroscopy (FTIR) that revealed the presence of NiFe and PANI , scanning electron microscopy (SEM) showed the uniform distribution of NiFe nanoparticles onto the surface of PANI, Energy-Dispersive X-ray spectroscopy (EDX) was utilized to validate the composition of the obtained Permalloy NiFe-PANI nanocomposites, optical properties confirmed the decrease of E g band gap from 2.62 to 2.51 eV by the addition of NiFe. The NiFe-PANI composite showed superior photocatalytic efficiency in degrading DCF, achieving 82.53% degradation in 15 min and 97.89% in 60 min. This was significantly higher than the PANI alone, which achieved 62.72 and 93.48% degradation in the same time intervals respectively. The results indicated that the photocatalytic efficiency remained consistent, with no observable decrease, even after five cycles of recycling. The NiFe-PANI catalyst served as an efficient and cost-effective photocatalyst for DCF degradation, and the study holds promise for the photocatalytic removal of other organic pollutants from water and wastewater.