High Thermoelectric Performance through Crystal Symmetry Enhancement in Triply Doped Diamondoid Compound Cu<sub>2</sub>SnSe<sub>3</sub>
Lei Hu, Yubo Luo, Yue‐Wen Fang, Feiyu Qin, Xun Cao, Hongyao Xie, Jiawei Liu, Jinfeng Dong, Andrea Sanson, Marco Giarola, Xianyi Tan, Yun Zheng, Ady Suwardi, Yizhong Huang, Kedar Hippalgaonkar, Jiaqing He, Wenqing Zhang, Jianwei Xu, Qingyu Yan, Mercouri G. Kanatzidis
Abstract
Abstract The presence of high crystallographic symmetry and nanoscale defects are favorable for thermoelectrics. With proper electronic structures, a highly symmetric crystal tends to possess multiple carrier channels and promote electrical conductivity without sacrificing Seebeck coefficient. In addition, nanoscale defects can effectively scatter acoustic phonons to suppress thermal conductivity. Here, it is reported that the triple doping of Cu 2 SnSe 3 leads to a high ZT value of 1.6 at 823 K for Cu 1.85 Ag 0.15 (Sn 0.88 Ga 0.1 Na 0.02 )Se 3 , and a decent average ZT ( ZT ave ) value of 0.7 is also achieved for Cu 1.85 Ag 0.15 (Sn 0.93 Mg 0.06 Na 0.01 )Se 3 from 475 to 823 K. This study reveals: 1) Ag doping on Cu sites generates numerous point defects and greatly decreases lattice thermal conductivity. 2) Doping Mg or Ga converts the monoclinic Cu 2 SnSe 3 into a cubic structure. This symmetry enhancing leads to an increase in the effective mass from 0.8 m e to 2.6 m e ( m e , free electron mass) and the power factor from 4.3 µW cm −1 K −2 for Cu 2 SnSe 3 to 11.6 µW cm −1 K −2 . 3) Na doping creates dense dislocation arrays and nanoprecipitates, which strengthens the phonon scattering. 4) Pair distribution function analysis shows localized symmetry breakdown in the cubic Cu 1.85 Ag 0.15 (Sn 0.88 Ga 0.1 Na 0.02 )Se 3 . This work provides a standpoint to design promising thermoelectric materials by synergistically manipulating crystal symmetry and nanoscale defects.