Litcius/Paper detail

Determination of the crystalline size of hexagonal La<sub>1−<i>x</i></sub>Sr<sub><i>x</i></sub>MnO<sub>3</sub> (<i>x</i> = 0.3) nanoparticles from X-ray diffraction – a comparative study

Do Hung Manh, Tran Thi Ngoc Nha, Le Thi Hong Phong, Phạm Hồng Nam, Trần Đăng Thành, P.T. Phong

2023RSC Advances100 citationsDOIOpen Access PDF

Abstract

nanopowders were produced after 10 h of milling in a commercial high-energy SPEX 8000D shaker mill, and then they were heated at 700 °C and 800 °C to study the effect of calcined temperature on the crystallization of nanoparticles. The modified Scherrer, Williamson-Hall, size-strain, and Halder-Wagner methods were used to determine the crystallite sizes and the elastic properties, such as intrinsic strain, stress, and energy density, from the X-ray diffraction peak broadening analysis. The obtained results were then compared with one another. The difference in crystallite sizes calculated from the different methods was due to the different techniques.

Topics & Concepts

CrystalliteMaterials scienceScherrer equationNanoparticleNanomaterialsCalcinationX-ray crystallographyCrystallographyCrystallizationDiffractionParticle sizeGrain sizeAnalytical Chemistry (journal)MineralogyNanotechnologyChemical engineeringComposite materialChemistryOpticsMetallurgyPhysicsBiochemistryCatalysisEngineeringChromatographyMagnetic and transport properties of perovskites and related materialsMagnetic Properties of AlloysRare-earth and actinide compounds