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Optimizing single cell proteomics using trapped ion mobility spectrometry for label-free experiments

Dong‐Gi Mun, Firdous Ahmad Bhat, Husheng Ding, Benjamin J. Madden, Sekar Natesampillai, Andrew D. Badley, Kenneth L. Johnson, Ryan Kelly, Akhilesh Pandey

2023The Analyst23 citationsDOIOpen Access PDF

Abstract

resulted in a substantial gain in the depth of proteome coverage and in detecting proteins with low abundance. We used these optimized conditions for proteome profiling of sorted human primary T cells, which yielded an average of 365, 804, 1116, and 1651 proteins from single, five, ten, and forty T cells, respectively. Notably, we demonstrated that the depth of proteome coverage from a low number of cells was sufficient to delineate several essential metabolic pathways and the T cell receptor signaling pathway. Finally, we showed the feasibility of detecting post-translational modifications including phosphorylation and acetylation from single cells. We believe that such an approach could be applied to label-free analysis of single cells obtained from clinically relevant samples.

Topics & Concepts

ProteomeIon-mobility spectrometryMass spectrometryChemistryProteomicsIonFragmentation (computing)Quantitative proteomicsAnalytical Chemistry (journal)Computational biologyBiophysicsChromatographyBiochemistryBiologyGeneOrganic chemistryEcologyAdvanced Proteomics Techniques and ApplicationsMass Spectrometry Techniques and ApplicationsBiosensors and Analytical Detection
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