Visible-light-initiated regio- and stereoselective C(sp<sup>2</sup>)–H phosphorylation of enamides under transition-metal-free conditions
Ji‐Yu Tao, Qinghong Zhang, Tong‐Hao Zhu, Xin-Wen Xu, Kun Ni, Qiao Zhao, Zheng‐Bao Qin, Yu Zhang, Lili Zhao, Kai Zhao
Abstract
A visible-light-induced stereo- and regioselective phosphorylation of enamides with phosphine oxides under transition-metal-free conditions has been disclosed.
Topics & Concepts
ChemistryRegioselectivityStereoselectivityVisible spectrumTransition metalPhosphinePhosphorylationMetalStereochemistryPhotochemistryCatalysisOrganic chemistryBiochemistryOptoelectronicsPhysicsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsSynthesis and Catalytic Reactions