Ligand evolution on trigonal bipyramidal boron imidazolate cages for enhanced optical limiting
Junqiang Chen, Hai‐Xia Zhang, Zhi-Run Wang, Qin‐Long Hong, Jian Zhang
Abstract
We synthesized here a series of trigonal bipyramidal cages, [M 5 L 6 ], which can realized the modulations of stacking modes, conjugation degree, electronic push–pull effects and band gaps. BIF-141 achieves excellent optical limiting (OL) performance.
Topics & Concepts
Trigonal bipyramidal molecular geometryStackingImidazolateLimitingBoronCrystallographyLigand (biochemistry)ChemistryMaterials scienceTrigonal crystal systemInorganic chemistryCrystal structureOrganic chemistryReceptorMechanical engineeringBiochemistryEngineeringNonlinear Optical Materials StudiesAdvanced Fiber Laser TechnologiesPorphyrin and Phthalocyanine Chemistry