Helically chiral Pd(<scp>ii</scp>) complexes containing intramolecular Pd⋯Pd metallophilicity as circularly polarized molecular phosphors
Jinqiang Lin, Mo Xie, Xiaobao Zhang, Qin Gao, Xiaoyong Chang, Chao Zou, Wei Lu
Abstract
Pallas's shining helixes: single-helical and double-helical oligonuclear pincer-type palladium(<sc>ii</sc>) arylacetylide complexes exhibit circularly polarized phosphorescence with MMLCT parentages in fluid solutions.
Topics & Concepts
Intramolecular forcePhosphorChemistryCrystallographyMaterials scienceStereochemistryOptoelectronicsSynthesis and Properties of Aromatic CompoundsLuminescence and Fluorescent MaterialsMolecular Sensors and Ion Detection