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Low-frequency Resonant Photoacoustic Gas Sensor by Employing Hollow Core Fiber-Based O-Shaped Multipass Cells

Bo Zhang, Jiachen Jiang, Xian Zhang, Yunjiang Jia, Xiao-Song Zhu, Yi-Wei Shi

2023Analytical Chemistry14 citationsDOI

Abstract

A low-frequency flexible resonant photoacoustic (PA) gas sensor using an O-shaped multipass cell is demonstrated. The PA sensor employed a flexible gradually tapered leaky hollow core fiber (LHCF). The LHCF was bent to be an end-to-end structure to make full use of the incident light. Additionally, the two ends of the LHCF were put inside a single buffer chamber, yielding an equivalent H-type acoustic resonator. The geometric size was reduced thanks to the bending structure. The geometric length of the LHCF was 500 mm. A micro-electro-mechanical-systems electrical microphone was installed at the center of the resonant tube to detect the PA signal. The proposed PA gas sensor exhibited a first-order longitudinal resonance frequency of 408 Hz. Trace acetylene (C 2 H 2 ) was used as the target gas. The minimum detectable limit was calculated to be 25.8 parts-per-billion (ppb) with an average time of 400 s, which was 1.93 times higher than that of a single-pass PA gas sensor. The normalized noise-equivalent absorption coefficient and the PA cell constant were calculated to be 9.6 × 10 –9 W·cm –1 ·Hz –1/2 and 8295 Pa/W·cm –1, respectively. The PA gas sensor owns a low resonance frequency and can be used for detection of most of the polar gaseous molecules, especially suitable for gas molecules with a long V–T relation time, such as carbon monoxide and carbon dioxide.

Topics & Concepts

ChemistryMicrophoneTrace gasAnalytical Chemistry (journal)Bent molecular geometryResonance (particle physics)ResonatorSIGNAL (programming language)BendingAbsorption (acoustics)OpticsOptoelectronicsAtomic physicsAcousticsMaterials scienceComposite materialProgramming languageChromatographyComputer scienceSound pressureOrganic chemistryPhysicsSpectroscopy and Laser ApplicationsAdvanced Fiber Optic SensorsPhotonic Crystal and Fiber Optics