Gauging ambiphilicity of pseudo-halides<i>via</i>beryllium-trispyrazolylborato compounds
Chantsalmaa Berthold, Matthias Müller, Sergei I. Ivlev, Diego M. Andrada, Magnus R. Buchner
Abstract
to explore the origins of the preferred isomers. Thus, we have synthesised and characterised through NMR and IR spectroscopy as well as single crystal X-ray diffraction these complexes. A combination with quantum chemical calculations within the DFT framework enabled an in-depth understanding of the bonding modes and preferences of the investigated pseudo-halido ligands.
Topics & Concepts
HalideBerylliumChemistryInorganic chemistryMaterials scienceCombinatorial chemistryOrganic chemistrySynthesis and biological activityNonlinear Optical Materials ResearchOrganic and Molecular Conductors Research