Litcius/Paper detail

Saturated Bioisosteres of <i>ortho</i>‐Substituted Benzenes

Aleksandr Denisenko, Pavel Garbuz, Svitlana V. Shishkina, Nataliya M. Voloshchuk, Pavel K. Mykhailiuk

2020Angewandte Chemie International Edition209 citationsDOI

Abstract

Saturated bioisosteres of ortho-disubstituted benzenes (bicyclo[2.1.1]hexanes) were synthesized, characterized and validated. These cores were incorporated into the bioactive compounds Valsartan, Boskalid and Fluxapyroxad instead of the benzene ring. The saturated analogues showed a similar level of antifungal activity compared to that of Boskalid and Fluxapyroxad.

Topics & Concepts

BenzeneAntifungalChemistryRing (chemistry)Medicinal chemistryOrganic chemistryBiologyMicrobiologyOxidative Organic Chemistry ReactionsAsymmetric Synthesis and CatalysisOrganic Chemistry Cycloaddition Reactions