Theoretical and Experimental Understanding of Metal Single-Atom Electrocatalysts for Accelerating the Electrochemical Reaction of Lithium–Sulfur Batteries
Chong Xu, Bing Ding, Zengjie Fan, Chengyang Xu, Qizhen Xia, Peng Li, Hui Dou, Xiaogang Zhang
Abstract
Metal single-atom materials have attracted tremendous attention in the research field of lithium–sulfur (Li–S) batteries because they can effectively improve the reaction kinetics of sulfur cathodes. However, it is still difficult to determine the best metal single-atom catalyst for Li–S batteries, due to the lack of a unified measurement and evaluation method. Herein, a series of metal single-atom- and nitrogen-doped graphene materials (M-NG, M = Fe, Co, Ni, Ir, Ru) have been prepared as the catalysts for promoting the reaction kinetics of the sulfur reduction reaction process. Using rotating disk electrode measurements and density functional theory-based theoretical calculations, Ni-NG was screened out to be the best catalyst. It is found that Ni-NG materials can provide a kinetically favorable pathway for the reversible conversion of polysulfide conversion, thus increasing the utilization of sulfur. By coating the Ni-NG materials on the separator as a multifunctional interlayer, a commercially available sulfur cathode presents a stable specific capacity of 701.8 mAh g–1 at a current rate of 0.5C over 400 cycles. Even with a high sulfur loading of 3.8 mg cm–2, a high areal capacity of 4.58 mAh cm–2 can be achieved. This work will provide a fundamental understanding of efficient single-atom catalyst materials for Li–S batteries.