Influence of the Increasing Number of Organic Radicals on the Structural, Magnetic, and Electrochemical Properties of the Copper(II)–Dioxothiadiazole Family of Complexes
Mirosław Arczyński, Dawid Pinkowicz
Abstract
. Small differences between the redox events suggest that such compounds may be good candidates for new switchable materials, where the electron transfer between the metal and the ligand center is triggered by temperature, pressure, or light (valence tautomerism).
Topics & Concepts
ChemistryDensity functional theoryCopperElectrochemistryIntramolecular forceParamagnetismAntiferromagnetismIminiumInductive couplingMagnetic susceptibilityIonComputational chemistryCrystallographyPhysical chemistryCondensed matter physicsStereochemistryElectrodeOrganic chemistryElectrical engineeringPhysicsEngineeringMagnetism in coordination complexesMetal complexes synthesis and propertiesLanthanide and Transition Metal Complexes