Fabrication of High-Performance Nanofiltration Membrane Using Polydopamine and Carbon Nitride as the Interlayer
Lei Ma, Qiuyan Bi, Yuanhui Tang, Chao Zhang, Fuju Qi, Hao Zhang, Yifan Gao, Shiai Xu
Abstract
In order to recover lithium from brine with a high Mg2+/Li+ ratio, a positively charged nanofiltration (NF) membrane was prepared by depositing polydopamine (PDA)-coated graphitic carbon nitride (g-C3N4) as the interlayer (PDA-g-C3N4) and the interfacial polymerization (IP) of polyethyleneimine (PEI) and trimesoyl chloride (TMC) was carried out. Under optimal conditions, the water contact angle of the composite membrane is only 55.5° and the isoelectric point (IEP) is 6.01. The final positively charged NF membrane (M5) exhibits high permeance (10.19 L·m−2·h−1·bar−1) and high rejection of Mg2+ (98.20%) but low rejection of Li+ (13.33%). The separation factor (SF) is up to 48.08, and the Mg2+/Li+ ratio of the permeate is 0.036 in the simulated brine. In conclusion, the M5 membrane shows a good separation performance for salt lake brine (SF = 12.79 and Mg2+/Li+ ratio of the permeate = 1.43) and good fouling resistance. Therefore, the positively charged M5 membrane with PDA-g-C3N4 as the interlayer has the potential to be used for the recovery of lithium from brine.