Luminescent 2-phenylbenzothiazole cyclometalated Pt<sup>II</sup> and Ir<sup>III</sup> complexes with chelating P^O ligands
David Gómez de Segura, Rebeca Lara, Mónica Martínez-Junquera, Elena Lalinde, M. Teresa Moreno
Abstract
Cyclometalated (pbt)-based Pt II and Ir III complexes with a diphenylphosphino donor functionalized deprotonated acid display phosphorescence of monomers with remarkably higher quantum yields for Pt II than for Ir III derivatives.
Topics & Concepts
Excited statePhotoluminescenceIridiumPhosphorescenceDeprotonationLuminescenceCrystallographyChemistryIntermolecular forceQuantum yieldBand gapPhysical chemistryMaterials scienceMoleculeFluorescenceCatalysisPhysicsAtomic physicsIonOrganic chemistryOptoelectronicsQuantum mechanicsOrganic Light-Emitting Diodes ResearchOrganometallic Complex Synthesis and CatalysisMagnetism in coordination complexes