Ion implantation induced <i>p</i>-type conductivity in FeS<sub>2</sub> thin film
Rudra Narayan Chakraborty, Dipta Suryya Mahanta, Santu Mazumder, Kasilingam Senthilkumar
Abstract
Abstract In pursuing sustainable energy solutions, thin-film solar cells based on the Copper zinc tin sulfide (CZTS) absorber material have garnered significant attention due to their earth-abundant and non-toxic composition. However, the modest efficiency demonstrated by CZTS solar cells has prompted researchers to investigate novel approaches to improve their performance. An area of potential advancement entails the integration of appropriate hole transport layers (HTLs). In this simulation-based study, we focused on FeS 2 as a highly promising candidate for use as an HTL in CZTS-based solar cells. FeS 2 , traditionally considered n -type, was tailored to achieve p -type conductivity through the negative ion implantation (O, P, and As) process. 40 keV ion beam was utilized, with three doses (10 5 , 10 10 , 10 15 cm −2 ) applied for each ion beam. We demonstrate successful p -type doping of FeS 2 with a hole concentration of ∼10 20 cm −3 in case of 10 15 cm −2 dose, paving the way for its integration as an effective HTL within the CZTS solar cell structure.