Self-promoted solid-state covalent networking of Au<sub>25</sub>(SR)<sub>18</sub> through reversible disulfide bonds. A critical effect of the nanocluster in oxidation processes
Yuki Saito, Yukatsu Shichibu, Katsuaki Konishi
Abstract
-type nanocluster to mediate oxidation processes as well as the utility of the concept of dynamic covalent chemistry in the bottom-up construction of nanomaterials, which would widen the potential of ligand-protected nanoclusters.
Topics & Concepts
NanoclustersCovalent bondDisulfide bondCovalent organic frameworkSolid-stateChemical bondOxidation stateMaterials scienceChemistryPolymer chemistryNanotechnologyCatalysisOrganic chemistryPhysical chemistryBiochemistryNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in CatalysisGold and Silver Nanoparticles Synthesis and Applications