Polyrotaxane based leakage-proof and injectable phase change materials with high melting enthalpy and adjustable transition temperature
Guang‐Zhong Yin, Alba Marta López, Xiaomei Yang, Xiang Ao, Jose Hobson, De‐Yi Wang
Abstract
In this work, a series of advanced phase change materials (PCMs) were fabricated by using polyrotaxane (PLR) as \nsupports for encapsulating poly (ethylene glycol) (PEG). Phase-change enthalpy is mainly regulated by the \nPEG contents, whereas phase change temperature is controlled by PEG molecular weight. All PCMs have good \nform stabilities due to the good compatibility between PLR and PEG, and supporting ability of PLR. Given that \nthe PLR support itself has phase-transition properties, the resulting composites have high phase change enthalpies \n(116.1–162.2 J g -1) and very high enthalpy efficiency (>100%). It is a green and efficient preparation \nmethod because the whole preparation process did not involve organic solvents, and the material was prepared \nat room temperature. In addition, the obtained PCMs can be easily extruded and re-molded, which provides \ntechnical premise and convenience for the large-scale applications. As a typical application example, the \nPCMs showed its significant advantages in simulated solid-state disk model temperature regulation, which fully \ndemonstrates the practical and superior application value of the PCMs in the field of thermal management for \nelectronic devices.