Chemoselective hydrogenation of α,β-unsaturated aldehydes over Rh nanoclusters confined in a metal–organic framework
Qinglin Liu, Yinle Li, Yanan Fan, Cheng‐Yong Su, Guangqin Li
Abstract
Rh nanoclusters confined in metal–organic framework MIL-101 have been synthesized by double solvents method, exhibiting impressive catalytic activities and high selectivity towards chemoselective hydrogenation of α,β-unsaturated aldehyde.
Topics & Concepts
NanoclustersAldehydeSelectivityCatalysisChemoselectivityMetalChemistryOrganic chemistryOrganic synthesisPhotochemistryMetal-Organic Frameworks: Synthesis and ApplicationsAsymmetric Hydrogenation and CatalysisNanomaterials for catalytic reactions