The Sulfinylsulfonation of alkynes for β‐Sulfinyl alkenylsulfone
Zhansong Zhang, Qingmin Song, Chengjie Feng, Zikun Wang, Wanjun Zhao, Yongquan Ning, Yong Wu
Abstract
Here we report the sulfinylsulfonation of alkynes to afford β-sulfinyl alkenylsulfone products with a broad substrate scope, excellent functional group compatibility, and high yield. Moreover, the sulfinylsulfonation reaction of enyne can also be realized for constructing functionalized carbo- and heterocycles through a radical cascade cyclization process.
Topics & Concepts
EnyneCompatibility (geochemistry)Yield (engineering)ChemistryScope (computer science)Combinatorial chemistryComputer scienceOrganic chemistryMaterials scienceProgramming languageCatalysisComposite materialMetallurgySulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsCatalytic C–H Functionalization Methods