Three-Dimensional Mesoporous Ni-CeO2 Catalyst for Dry Reforming of Methane
Huiyao Jin, Yuanqiao Liu, Lizhi Huang, Yali Liu, Sha Cui, Hui Liu, Jing Xu, Luhui Wang
Abstract
Using the colloidal solution combustion approach, a three-dimensional mesoporous 5%Ni-CeO2-M catalyst was developed, with Ni incorporated into the pores, and applied in the dry reforming of methane. Comprehensive characterization revealed that the 5%Ni-CeO2-M catalyst had a large specific surface area and a three-dimensional mesoporous structure. A rich Ni-CeO2 interface was formed by closely spaced tiny CeO2 and NiO nanoparticles within the spherical pore wall. With very little carbon deposition over a 100 h period at 700 °C, the catalyst showed excellent activity and stability. The tiny Ni nanoparticles, along with the substantial Ni-CeO2 interfaces that make up this three-dimensional in-form mesoporous catalyst, are responsible for the outstanding effectiveness of this 5%Ni-CeO2-M catalyst.