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Molecular Main Group Metal Hydrides

Matthew M. D. Roy, Alvaro A. Omaña, Andrew S. S. Wilson, Michael S. Hill, Simon Aldridge, Eric Rivard

2021Chemical Reviews286 citationsDOI

Abstract

This review serves to document advances in the synthesis, versatile bonding, and reactivity of molecular main group metal hydrides within Groups 1, 2, and 12-16. Particular attention will be given to the emerging use of said hydrides in the rapidly expanding field of Main Group element-mediated catalysis. While this review is comprehensive in nature, focus will be given to research appearing in the open literature since 2001.

Topics & Concepts

ChemistryGroup (periodic table)Reactivity (psychology)Main group elementMetalNanotechnologyCombinatorial chemistryCatalysisOrganic chemistryTransition metalPathologyMedicineMaterials scienceAlternative medicineAsymmetric Hydrogenation and CatalysisOrganoboron and organosilicon chemistryCoordination Chemistry and Organometallics
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