Effect of silica dispersed by special dispersing agents with green strategy on tire rolling resistance and energy consumption
Xingfu Zheng, Shi Kai Song, Ziwen Zhou, Xizhou Jiang, Yongqiang Sui, Mingming Che, Qi Xu, Yan Wang, Shuai Zhao, Lin Li
Abstract
Abstract The state‐of‐art approach to realize the low rolling resistance of green tires is the high addition of SiO 2 . However, its dispersion capacity and the interface strength with rubber dominant the final properties of green tires. Here, we systematically study amphiphilic polyoxyethylene sorbitan monooleate, oleylamine, sorbitan monooleate, and oleamide to modify SiO 2 through simple hydrogen‐bonded self‐assembly in order to replace the traditional silane coupling agent with low modification efficiency, many side reactions and complex reaction process. The results show that the rolling resistance and processing energy loss of the rubber composite prepared by SiO 2 modified with polyoxyethylene sorbitan monooleate and oleylamine are significantly reduced, and other physical and mechanical properties (tensile strength, tear strength, and wear resistance) are also significantly improved compared with the silane coupling agent commonly used in green tire tread. Meanwhile, carbon–carbon double bonds belonging to polyoxyethylene sorbitan monooleate and oleylamine can participate in vulcanization of rubber to strongly improve the dispersion ability of SiO 2 and the interface interaction between SiO 2 and rubber matrix, so as to develop the fuel‐efficient green tire tread with high performance and low rolling resistance.