Halogen bonding in cadmium(<scp>ii</scp>) MOFs: its influence on the structure and on the nitroaldol reaction in aqueous medium
Atash V. Gurbanov, Maxim L. Kuznetsov, Anirban Karmakar, Vusala A. Aliyeva, Kamran T. Mahmudov⧫, Armando J. L. Pombeiro
Abstract
Attaching iodine atoms to an arylhydrazone ligand results in the formation of noncovalent interactions and enhances the solubility of the corresponding MOFs which act as homogeneous catalyst precursors in the nitroaldol reaction.
Topics & Concepts
ChemistryIsophthalic acidSupramolecular chemistryIntramolecular forceHalogen bondIntermolecular forceHalogenSolventPolymer chemistryIsostructuralCatalysisMedicinal chemistryAqueous solutionStereochemistryCrystallographyMoleculeHydrogen bondCrystal structureOrganic chemistryTerephthalic acidAlkylPolyesterMetal-Organic Frameworks: Synthesis and ApplicationsCrystallography and molecular interactionsCrystal structures of chemical compounds