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Molecular dynamics simulations of copolymer compatibilizers for polylactide/poly(butylene succinate) blends

Orrasa Prasitnok, Khongvit Prasitnok

2023Physical Chemistry Chemical Physics15 citationsDOI

Abstract

linear and branch) and the monomer sequence of the copolymers were found to affect the tensile performance. The system with a diblock copolymer showed a much greater tensile strength and elastic modulus than the other compatibilized blends. Comparing between triblock and graft copolymers, the former yielded the blends with better tensile performance than the latter. Our results suggest that copolymers with a linear structure, especially the diblock one, could be good candidates for the compatibilizer of PLA/PBS blends.

Topics & Concepts

CopolymerMaterials scienceUltimate tensile strengthMolecular dynamicsMonomerComposite materialCompatibilizationPolymer blendModulusDeformation (meteorology)Polymer chemistryPolymerChemistryComputational chemistrybiodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionPolymer crystallization and properties
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