Synergistic crystalline catalysts assembled with Wells–Dawson-type polyoxometalates and heterovalent metal complexes for efficient benzylic C–H bond oxidation
Ze-Xuan Liu, Jing Du, Shuai Li, Miao-Qi Zhu, Yuan‐Yuan Ma, Zhangang Han
Abstract
Two synergistic crystalline catalysts assembled with Wells–Dawson-type [P 2 W 18 O 62 ] 6− cluster and heterovalent Cu complexes were synthesized for benzylic C–H oxidation, with high DPM conversion and a distinct radical-mediated oxidation mechanism.
Topics & Concepts
PolyoxometalateCatalysisMetalChemistryMaterials scienceInorganic chemistryOrganic chemistryOxidative Organic Chemistry ReactionsChemical Synthesis and ReactionsPolyoxometalates: Synthesis and Applications