Memristor Based on TiO<sub> <i>x</i> </sub>/Al<sub>2</sub>O<sub>3</sub> Bilayer as Flexible Artificial Synapse for Neuromorphic Electronics
Facai Wu, Peng Cao, Zehui Peng, Shanwu Ke, Gong Cheng, Guangsen Cao, Bei Jiang, Cong Ye
Abstract
Flexible memristor is one of the most promising wearable devices for abundant data storage and processing. In this work, interface engineering by inserting the Al <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> barrier layer is carried out to construct Pt/TiO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"><i>x</i></sub> /Al <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Pt/indium tin oxide (ITO) flexible artificial synapse device. The memristor performance can be maintained even under 1000 times of bending without degradation, demonstrating its excellent mechanical property. With the Al <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> diffusion barrier layer, the oxygen vacancies ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${V}_{\text {o}}$ </tex-math></inline-formula> ) movement is slowed down for filaments formation and rupture, thus it boosts up the synaptic plasticity, including long-term potentiation/depression, paired-pulse facilitation (PPF), and spike-timing-dependent plasticity (STDP). Moreover, on the basis of the enhanced symmetry and linearity of conductance for Pt/TiO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"><i>x</i></sub> /Al <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Pt/indium tin oxide (ITO) memristor, the neural network simulation for supervised learning presents an online learning pattern recognition, the accuracy can achieve to 91.15%. Overall, the Pt/TiO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"><i>x</i></sub> /Al <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Pt/ITO memristor with excellent flexibility is a promising emulator for biological synapses, which could be beneficial to future flexible memristor-based neuromorphic computing.