Acetylene semi-hydrogenation catalyzed by Pd single atoms sandwiched in zeolitic imidazolate frameworks <i>via</i> hydrogen activation and spillover
Yanting Li, Wen‐Gang Cui, Ying-Fei Huo, Lei Zhou, Xinqiang Wang, Fan Gao, Qiang Zhang, Wei Li, Tong‐Liang Hu
Abstract
Pd single atoms were anchored by zeolitic imidazolate framework to form a Z@Pd@Z sandwich catalyst, over which efficient acetylene semi-hydrogenation could be realized by hydrogen activation and spillover.
Topics & Concepts
Zeolitic imidazolate frameworkImidazolateHydrogen spilloverCatalysisAcetyleneSpillover effectMaterials scienceHydrogenMetal-organic frameworkChemical engineeringChemistryInorganic chemistryOrganic chemistryAdsorptionMicroeconomicsEngineeringEconomicsCatalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesMetal-Organic Frameworks: Synthesis and Applications