Interface Modification Uncovers the Potential Application of SnO<sub>2</sub>/TiO<sub>2</sub> Double Electron Transport Layer in Efficient Cadmium‐Free Sb<sub>2</sub>Se<sub>3</sub> Devices
Weihuang Wang, Liquan Yao, Jiabin Dong, Li Wu, Zixiu Cao, Hui Li, Guilin Chen, Jingshan Luo, Yi Zhang
Abstract
Abstract An undesirable p–n heterojunction interface of Sb 2 Se 3 absorber with Cd‐free electron transport layer (ETL) is one of the key problems hindering the efficiency improvement of Sb 2 Se 3 solar cell. Herein, a promising SnO 2 /TiO 2 ETL coupled with SbCl 3 treatment is introduced to improve the performance of Sb 2 Se 3 solar cell. The mechanism of SbCl 3 treatment on the crystal orientation of Sb 2 Se 3 thin film and the p–n heterojunction interface of Sb 2 Se 3 solar cell is disclosed combined with different characterization methods. The carrier transport property for Sb 2 Se 3 thin film is enhanced, and the conduction band offset (CBO) of TiO 2 /Sb 2 Se 3 interface is reduced from 0.57 to 0.20 eV by forming Sb 2 O 3 interlayer at TiO 2 /Sb 2 Se 3 interface after SbCl 3 treatment, by which the interface recombination and the open circuit voltage deficit of the device can be effectively decreased, and the interface bonding at TiO 2 /Sb 2 Se 3 interface can be effectively improved. Ultimately, the Cd‐free Sb 2 Se 3 solar cell with configuration of ITO/SnO 2 /TiO 2 /Sb 2 Se 3 /Au achieves an efficiency of 5.82%, which is the highest efficiency in vapor transport deposition (VTD)‐processed Cd‐free Sb 2 Se 3 solar cell at present. This work is expected to fill in the blank of VTD‐processed Cd‐free Sb 2 Se 3 solar cell and offers a valuable reference for future band alignment of Sb 2 Se 3 solar cell.