Selective<i>N</i>-formylation/<i>N</i>-methylation of amines and<i>N</i>-formylation of amides and carbamates with carbon dioxide and hydrosilanes: promotion of the basic counter anions of the zinc catalyst
Qiao Zhang, Xiao-Tao Lin, Norihisa Fukaya, Tadahiro Fujitani, Kazuhiko Sato, Jun‐Chul Choi
Abstract
A Zn(OAc)<sub>2</sub>catalyst bearing the 1,10-phenanthroline (phen) ligand was efficient in the<italic>N</italic>-formylation of organic amine derivatives (<italic>e.g.</italic>, amines, amides, and carbamates) using carbon dioxide (CO<sub>2</sub>) and hydrosilanes.
Topics & Concepts
FormylationChemistryCarbon dioxideMedicinal chemistryAmine gas treatingLigand (biochemistry)CatalysisOrganic chemistryReceptorBiochemistryCarbon dioxide utilization in catalysisAsymmetric Hydrogenation and CatalysisChemical Synthesis and Reactions