How to make C–N bonds using boronic acids and their derivatives without transition metals
Silvia Roscales, Aurelio G. Csákÿ
Abstract
This tutorial review describes recent developments in carbon-nitrogen bond-forming reactions (amination, amidation, nitration and nitrosation) that involve the use of boronic acids and some of their derivatives as carbon-nucleophiles in the absence of transition-metals. Issues pertaining to reagents and mechanisms are discussed.
Topics & Concepts
AminationNitrationChemistryTransition metalReagentCatalysisBoronCombinatorial chemistryOrganic chemistryNitrosationOrganoboron and organosilicon chemistryChemical Synthesis and AnalysisChemical Synthesis and Reactions