Litcius/Paper detail

Construction of sulfonated spiro[5,5]trienones from sulfur dioxide <i>via</i> iron-catalyzed dearomative spirocyclization of biaryls

Fu‐Sheng He, Lingjing Su, Feiyan Yu, Zhimei Tang, Jie Wu

2022Organic Chemistry Frontiers39 citationsDOI

Abstract

An iron-catalyzed dearomative spirocyclization of biaryl ynones with sodium metabisulfite and cycloketone oxime esters is developed for the construction of sulfonated spiro[5,5]trienones.

Topics & Concepts

ChemistrySulfur dioxideSodium metabisulfiteOximeCatalysisSulfurOrganic chemistryCombinatorial chemistrySulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsCatalytic C–H Functionalization Methods