Monoarsine-protected icosahedral cluster [Au<sub>13</sub>(AsPh<sub>3</sub>)<sub>8</sub>Cl<sub>4</sub>]<sup>+</sup>: comparative studies on ligand effect and surface reactivity with its stibine analogue
Jiu‐Hong Yu, Zhi‐Rui Yuan, Jing Xu, Jingui Wang, Mohammad Azam, Tianduo Li, Ying‐Zhou Li, Di Sun
Abstract
The arsine-protected cluster [Au 13 (AsPh 3 ) 8 Cl 4 ] + holds greater potential to enable a better trade-off between catalytic stability and activity, whilst it is also surface reactive and suitable for further derivatization by ligand exchange.
Topics & Concepts
StibineChemistryArsineIcosahedral symmetryCluster (spacecraft)Reactivity (psychology)Ligand (biochemistry)CatalysisPhysical chemistryInorganic chemistryCrystallographyPhosphineOrganic chemistryReceptorBiochemistryPathologyComputer scienceAlternative medicineProgramming languageMedicineNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in CatalysisPharmacological Effects and Toxicity Studies