Visible-light-mediated synthesis of non-anomeric<i>S</i>-aryl glycosides<i>via</i>a photoactive electron-donor–acceptor complex
Le Zhang, Shiyun He, Jinyu Hou, Meiling Ye, Jian Chen, Guanghui Lv, Tianle Huang, Zhongzhen Yang, Yong Wu
Abstract
A visible-light-mediated glycosylation reaction between glycosyl redox-active esters and disulfides has been reported, through which a series of S -aryl glycosides were obtained in good yields with satisfactory stereoselectivity.
Topics & Concepts
AnomerArylAcceptorChemistryPhotochemistryElectron donorElectron acceptorVisible spectrumGlycosideStereochemistryCombinatorial chemistryOrganic chemistryCatalysisMaterials sciencePhysicsAlkylOptoelectronicsCondensed matter physicsCarbohydrate Chemistry and SynthesisSulfur-Based Synthesis TechniquesRadical Photochemical Reactions