Direct acylation and alkynylation of hydrocarbons <i>via</i> synergistic decatungstate photo-HAT/nickel catalysis
Wenfeng Liu, Yang Ke, Chuhan Liu, Wangqing Kong
Abstract
)-H bonds of saturated hydrocarbons by synergistic decatungstate photo-HAT and nickel catalysis. This method, using cheap and easy-to-synthesize TBADT as a HAT photocatalyst, exhibits excellent site selectivity. A wide variety of high-value ketones, amides, esters, and diverse alkynes can be efficiently constructed from abundant hydrocarbon feedstocks.
Topics & Concepts
AlkynylationAcylationCatalysisChemistryNickelHydrocarbonSelectivityPhotocatalysisCombinatorial chemistryPhotochemistryOrganic chemistryCatalytic C–H Functionalization MethodsSulfur-Based Synthesis TechniquesRadical Photochemical Reactions