Different effects of metal-NHC bond cleavage on the Pd/NHC and Ni/NHC catalyzed α-arylation of ketones with aryl halides
Konstantin E. Shepelenko, Safarmurod B. Soliev, Alexey S. Galushko, Victor M. Chernyshev, Valentine P. Ananikov
Abstract
Fundamental differences in the behavior of Pd/NHC and Ni/NHC catalytic systems in ketones α-arylation were elucidated and exploited.
Topics & Concepts
HalideCatalysisArylChemistryMetalCleavage (geology)Medicinal chemistryBond cleavageOrganic chemistryMaterials scienceAlkylFracture (geology)Composite materialCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsCatalytic Alkyne Reactions