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Investigation on the predictive power of tolerance factor <i>τ</i> for A-site double perovskite oxides

Elisabeth K. Albrecht, Antti J. Karttunen

2023Dalton Transactions51 citationsDOIOpen Access PDF

Abstract

predicts high probability for their existence. In both cases, we found limits in the predictive power of the new tolerance factor for ion combinations on the A and A' site which are very different in size. A difference in oxidation state may decrease the accuracy, as well. Overall, the A-site double perovskite stability mapping provides a starting point for the discovery of novel A-site double perovskites.

Topics & Concepts

Perovskite (structure)Quantum chemicalPredictive powerFactor (programming language)Power (physics)Materials scienceChemistryComputer sciencePhysicsCrystallographyThermodynamicsQuantum mechanicsMoleculeOrganic chemistryProgramming languagePerovskite Materials and ApplicationsCrystal Structures and PropertiesAdvanced Condensed Matter Physics
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