Tetrazole-based porous metal–organic frameworks for selective CO<sub>2</sub> adsorption and isomerization studies
Rui Zhang, De-Xian Meng, Fa-Yuan Ge, Jv-Hua Huang, Lifei Wang, Yong-Kai Xv, Xing-Gui Liu, Mei-Mei Meng, Hong Yan, Zhenzhong Lu, He‐Gen Zheng, Wei Huang
Abstract
, which should be attributed to the high density of free nucleophilic tetrazole N atoms on the pore surfaces. We found that the isomerization between 2 and 3 was caused by the diverse coordination modes of tetrazole-based ligands and can be controlled in synthesis processes.
Topics & Concepts
TetrazoleIsomerizationMetal-organic frameworkAdsorptionPorosityMaterials scienceSelective adsorptionChemical engineeringMetalChemistryPhotochemistryOrganic chemistryCatalysisEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsCarbon dioxide utilization in catalysis