Activation of DMSO(-d<sub>6</sub>) <i>via</i> heterogeneous photo-Fenton-like process with <i>in situ</i> production of hydroxyl radicals for the C–H (trideutero)methylation of (iso)quinoliniums
Palani Natarajan, Aleyna Basak, Önder Metin
Abstract
All Fenton reagent-assisted DMSO activation and in situ ˙CH 3 -radical production reported yet exclusively employ homogeneous reagent systems. However, the method described herein is based on the use of a heterogeneous photo-Fenton-like system.
Topics & Concepts
ReagentRadicalIn situChemistryHomogeneousHydroxyl radicalFenton's reagentFenton reactionMethylationProcess (computing)PhotochemistryCombinatorial chemistryOrganic chemistryBiochemistryComputer scienceOperating systemPhysicsThermodynamicsGeneChemical Reactions and IsotopesRadical Photochemical ReactionsAmmonia Synthesis and Nitrogen Reduction