A Complex Concentrated Alloy with Record‐High Strength‐Toughness at 77 K
Yasir Sohail, Chongle Zhang, Shaohua Gao, Jinyu Zhang, Wenli Song, Xuanzhe Li, Bo Wang, Suzhi Li, Dezhen Xue, Gang Liu, Emad Maawad, Weimin Gan, E. Ma, Jun Sun
Abstract
Abstract High strength and large ductility, leading to a high material toughness (area under the stress‐strain curve), are desirable for alloys used in cryogenic applications. Assisted by domain‐knowledge‐informed machine learning, here a complex concentrated Fe 35 Co 29 Ni 24 Al 10 Ta 2 alloy is designed, which uses L1 2 coherent nanoprecipitates in a high volume fraction (≈65 ± 3 vol.%) in a face‐centered‐cubic (FCC) solid solution matrix that undergoes FCC‐to‐body‐centered‐cubic (BCC) phase transformation upon tensile straining. Unlike FCC‐to‐BCT phase transformation involving brittle carbon‐enriched martensite, the BCC martensite in this alloy does not cause brittleness at 77 K. The Fe 35 Co 29 Ni 24 Al 10 Ta 2 multi‐principal element alloy achieves a high yield strength ≈1.4 GPa, a high work hardening rate >4 GPa, an ultimate tensile strength ≈2.25 GPa, and a large uniform elongation ≈45%, leading to record‐high material toughness compared with previous cryogenic alloys such as 316L series stainless steels and recent high‐entropy alloys. The nanoprecipitates with nanoscale spacing (≈7.5 nm), apart from serving as dislocation obstacles for strengthening and dislocation sources for sustainable ductility, also undergo deformation twinning. Taken together, these mechanisms are found to be highly effective in strengthening and strain hardening upon tensile straining at liquid nitrogen temperature. These findings demonstrate how to effectively integrate strengthening mechanisms to synergize superior mechanical properties in special‐purpose alloys.