Enhanced water stability and high CO<sub>2</sub> storage capacity of a Lewis basic sites-containing zirconium metal–organic framework
Selçuk Demir, Nuray Bilgin, Hamide Merve Çepni, Hiroyasu Furukawa, Fatih Yılmaz, Çiğdem Altıntaş, Seda Keskın
Abstract
MOF-553 with its 6,6′-dimethyl-2,2′-bipyridine-5,5′-dicarboxylate linker is more robust and has a higher CO 2 adsorption capacity than the 2,2′-bipyridine-5,5′-dicarboxylate containing UiO-67(bipy) MOF.
Topics & Concepts
Metal-organic frameworkLinkerZirconiumThermal stabilityAdsorptionLewis acids and basesChemical stabilityChemistryCarboxylateHydrolysisBipyridineInorganic chemistryCombinatorial chemistryPolymer chemistryChemical engineeringOrganic chemistryCatalysisEngineeringCrystal structureOperating systemComputer scienceMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsMembrane Separation and Gas Transport