Recent advances in the application of alcohols in extracting lignin with preserved β-O-4 content from lignocellulosic biomass
Khai Jie Yong, Ta Yeong Wu
Abstract
Utilizing lignocellulosic biomass wastes to produce bioproducts is essential to address the reliance on depleting fossil fuels. However, lignin is often treated as a low-value-added component in lignocellulosic wastes. Valorization of lignin into value-added products is crucial to improve the economic competitiveness of lignocellulosic biorefinery. Monomers obtained from lignin depolymerization could be upgraded into fuel-related products. However, lignins obtained from conventional methods are low in β-O-4 content and, therefore, unsuitable for monomer production. Recent literature has demonstrated that lignins extracted with alcohol-based solvents exhibit preserved structures with high β-O-4 content. This review discusses the recent advances in utilizing alcohols to extract β-O-4-rich lignin, where discussion based on different alcohol groups is considered. Emerging strategies in employing alcohols for β-O-4-rich lignin extraction, including alcohol-based deep eutectic solvent, flow-through fractionation, and microwave-assisted fractionation, are reviewed. Finally, strategies for recycling or utilizing the spent alcohol solvents are also discussed.