Dancing silanols: stereospecific rearrangements of silanol epoxides into silanoxy-tetrahydrofurans and silanoxy-tetrahydropyrans
Harshit Joshi, Annu Anna Thomas, Joel T. Mague, Shyam Sathyamoorthi
Abstract
We have developed highly stereospecific rearrangements of silanol epoxides into 1′-silanoxy-tetrahydrofurans and 1′-silanoxy-tetrahydropyrans.
Topics & Concepts
ChemistryStereospecificitySilanolEpoxideDiastereomerStereochemistryOrganic chemistryCatalysisTraditional and Medicinal Uses of AnnonaceaeMarine Sponges and Natural ProductsSynthetic Organic Chemistry Methods