Two-Dimensional TiO2 Ultraviolet Filters for Sunscreens
Ruoning Yang, Jiefu Chen, Xiang Li, Yaxin Zhang, Baofu Ding, Yuanjie Xu, S. Luo, Shaohua Ma, Xingang Ren, Gang Liu, Ling Qiu, Hui–Ming Cheng
Abstract
Abstract Titanium dioxide (TiO 2 ) has been an important protective ingredient in mineral-based sunscreens since the 1990s. However, traditional TiO 2 nanoparticle formulations have seen little improvement over the past decades and continue to face persistent challenges related to light transmission, biosafety, and visual appearance. Here, we report the discovery of two-dimensional (2D) TiO 2 , characterized by a micro-sized lateral dimension (~1.6 μm) and atomic-scale thickness, which fundamentally resolves these long-standing issues. The 2D structure enables exceptional light management, achieving 80% visible light transparency—rendering it nearly invisible on the skin—while maintaining UV-blocking performance comparable to unmodified rutile TiO 2 nanoparticles. Its larger lateral size results in a two-orders-of-magnitude reduction in skin penetration (0.96 w/w%), significantly enhancing biosafety. Moreover, the unique layered architecture inherently suppresses the generation of reactive oxygen species (ROS) under sunlight exposure, reducing the ROS generation rate by 50-fold compared to traditional TiO 2 nanoparticles. Through precise metal element modulation, we further developed the first customizable sunscreen material capable of tuning UV protection ranges and automatically matching diverse skin tones. The 2D TiO 2 offers a potentially transformative approach to modern sunscreen formulation, combining superior UV protection, enhanced safety and a natural appearance.