Managing Excess Lead Iodide with Functionalized Oxo‐Graphene Nanosheets for Stable Perovskite Solar Cells
Guixiang Li, Yalei Hu, Meng Li, Ying Tang, Zuhong Zhang, Artem Musiienko, Qing Cao, Fatima Akhundova, Jinzhao Li, Karunanantharajah Prashanthan, Fengjiu Yang, Patryk Janasik, Augustine Nana Sekyi Appiah, Sergei Trofimov, Nikolaos Livakas, Shengnan Zuo, Luyan Wu, Luyao Wang, Yuqian Yang, Benjamin Agyei‐Tuffour, Rowan W. MacQueen, Boris Naydenov, Thomas Unold, Eva Unger, Ece Aktas, Siegfried Eigler, Antonio Abate
Abstract
Abstract Stability issues could prevent lead halide perovskite solar cells (PSCs) from commercialization despite it having a comparable power conversion efficiency (PCE) to silicon solar cells. Overcoming drawbacks affecting their long‐term stability is gaining incremental importance. Excess lead iodide (PbI 2 ) causes perovskite degradation, although it aids in crystal growth and defect passivation. Herein, we synthesized functionalized oxo‐graphene nanosheets (Dec‐oxoG NSs) to effectively manage the excess PbI 2 . Dec‐oxoG NSs provide anchoring sites to bind the excess PbI 2 and passivate perovskite grain boundaries, thereby reducing charge recombination loss and significantly boosting the extraction of free electrons. The inclusion of Dec‐oxoG NSs leads to a PCE of 23.7 % in inverted (p‐i‐n) PSCs. The devices retain 93.8 % of their initial efficiency after 1,000 hours of tracking at maximum power points under continuous one‐sun illumination and exhibit high stability under thermal and ambient conditions.