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Methanol from solid fuels: A cost-effective route to reduced emissions and enhanced energy security

Carlos Arnaiz del Pozo, Ángel Jiménez Álvaro, Schalk Cloete

2022Energy Conversion and Management10 citationsDOIOpen Access PDF

Abstract

Methanol (MeOH) is gaining increasing relevance as a future energy carrier. It can be produced through multiple avenues, including locally available solid fuels where the CO2 footprint of coal-derived MeOH can be strongly reduced through co-gasification with biomass and integration of CO2 capture and storage. This work presents a techno-economic assessment of five MeOH production processes from a 70/30 %w. coal/biomass blend under consistent cost assumptions of 2.5 €/GJ coal, 100 €/ton (6.1 €/GJ) biomass, 100 €/ton CO2 tax and 60 €/MWh carbon-free electricity. The reference plant configuration reached a levelized cost of MeOH (LCOM) of 285.5 €/ton, while the two advanced concepts with a more efficient gasification system reached costs of 245.0–255.0 €/ton. Two additional cases synergistically integrating PEM electrolysers to deliver H2 for improving the syngas H/C ratio and O2 for gasification reached higher LCOM of 363.0–448.8 €/ton due to the higher cost contribution of electricity. An unrealistically low price of 25.6–34.7 €/MWh for a steady-state supply of carbon-free electricity is required for these configurations to break even with the benchmark plant. Finally, MeOH from the best performing plant was shown to be cost-competitive with gasoline produced from 60 €/barrel oil, while total CO2 emissions (including combustion) were 56 % lower. Thus, MeOH from solid fuels offers a cost-effective solution to climate change and energy security in energy importing regions.

Topics & Concepts

TonCost of electricity by sourceCoalSyngasBiomass (ecology)Waste managementIntegrated gasification combined cycleEnvironmental scienceElectricityGasolineElectricity generationCombustionRefineryEnergy securityEngineeringChemistryRenewable energyCatalysisPower (physics)OceanographyFisheryOrganic chemistryBiochemistryPhysicsQuantum mechanicsBiologyElectrical engineeringGeologyCO2 Reduction Techniques and CatalystsCatalysts for Methane ReformingElectrocatalysts for Energy Conversion
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